When you radiometrically date a mineral grain you are determining when it crystallized. Thus, you would like to use rocks whose crystals are roughly the same age. The easiest are igneous rocks in which all crystals are roughly the same age, having solidified at about the same time.

What is most effective for absolute dating?

carbon-14 One of the most widely used and well-known absolute dating techniques is carbon-14 (or radiocarbon) dating, which is used to date organic remains. This is a radiometric technique, since it is based on radioactive decay.